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## ERQ · 12 marks · Topics: A.3 Work, energy and power + B.5 Current and circuits · Archetype: theory_application
**Integration:** primary=A.3 Work, energy and power, secondary=B.5 Current and circuits (strength: supporting)
**Stem.** A student investigates the efficiency of an electrical heater in a laboratory calorimeter. A heating resistor is fully immersed in 0.50 kg of water held in an insulated calorimeter. The resistor is connected to a variable DC supply, with an ammeter in series and a voltmeter across the resistor. With the supply adjusted, the ammeter reads a steady 2.5 A and the voltmeter reads a steady 12 V. The current is maintained for 180 s, during which the temperature of the water rises by 8.2 K. The specific heat capacity of water is 4200 J kg⁻¹ K⁻¹; assume the initial water temperature is close to room temperature.
### Part (a) State [2 marks] · AO1 · Topic: B.5
State what is meant by *electrical power* and give its SI unit.
### Part (b)(i) Calculate [3 marks] · AO2 · Topic: B.5
Calculate the electrical power dissipated in the heating resistor.
### Part (b)(ii) Determine [2 marks] · AO2 · Topic: A.3
Determine the total electrical energy supplied to the resistor during the 180 s.
### Part (c) Calculate [3 marks] · AO2 · Topic: A.3
Calculate the thermal energy absorbed by the water during the 180 s, and state the difference between this value and the electrical energy supplied.
### Part (d) Suggest [2 marks] · AO3 · Topic: A.3 · ASSUMPTIONS DISCRIMINATOR
The student's model assumes that all electrical energy supplied to the resistor is transferred to the water as thermal energy. Suggest, with reference to one specific assumption that fails in the real system, why the thermal energy absorbed by the water in (c) is less than the electrical energy supplied in (b)(ii).
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## Mark Scheme
### Part (a) [2 marks]
- M1: power is the rate of transfer of (electrical) energy / energy transferred per unit time / P = energy/time OR P = IV with symbols defined [no ECF]
- M2: SI unit is the watt (W) / J s⁻¹ [no ECF]
### Part (b)(i) [3 marks] — Calculate
- M1: uses P = IV (relevant equation identified with substitution) [no ECF]
- M2: substitution shown: P = 12 × 2.5 [no ECF]
- M3: P = 30 W [no ECF]
### Part (b)(ii) [2 marks] — Determine
- M1: uses E = Pt with substitution E = 30 × 180 [ECF from (b)(i)]
- M2: E = 5400 J / 5.4 kJ [ECF from (b)(i)]
### Part (c) [3 marks] — Calculate
- M1: uses Q = mcΔT with substitution Q = 0.50 × 4200 × 8.2 [no ECF]
- M2: Q = 17 220 J ≈ 1.72 × 10⁴ J [no ECF]
- M3: states that Q > E_electrical (by ≈ 1.18 × 10⁴ J) / electrical energy supplied is INSUFFICIENT to account for the temperature rise observed [ECF from (b)(ii) and M2]
### Part (d) [2 marks] — Suggest (proposal + reasoning per §4.4.1)
- M1: identifies ONE specific failing assumption from the model. Award only for a single, specific assumption named explicitly. Acceptable examples: "the assumption that the water is initially in thermal equilibrium with surroundings (no prior heating)" / "the assumption that the calorimeter walls and resistor itself absorb negligible energy" / "the assumption that I and V remain constant — resistance changes with temperature" / "the assumption that no thermal energy enters from the room/the assumption Q_loss = 0". Do NOT award for vague statements such as "energy is lost" or "the system is not perfect" without naming a specific assumption.
- M2: explains the physical mechanism by which that named assumption fails, linked to the discrepancy in (c). The mechanism must reference a directional energy transfer or a changing quantity. Acceptable examples linked to M1: "the water was already above room temperature, so heat flowed in from the surroundings adding to the temperature rise" / "the resistance of the heater decreases / increases with T so the true P during the 180 s differs from 30 W, meaning Pt underestimates the actual electrical input" / "the calorimeter was warmer than the room, so net heat inflow from surroundings supplemented the electrical energy". Do NOT award M2 if M1 is not awarded; do NOT award M2 for restating M1 without a mechanism.
### Marker notes
- Note that in (c) the calculated Q EXCEEDS the electrical energy supplied — this is the intended pedagogical inversion of the standard "losses" scenario and forces the student in (d) to reason about energy INPUTS from surroundings rather than reciting "heat lost to surroundings". Reject any (d) response invoking "heat lost to surroundings causes Q < E_electrical" as it contradicts the numerical result of (c).
- Accept ECF in (c) M3 if a student's E_electrical from (b)(ii) leads to Q < E_electrical; in that case (d) responses citing standard losses (radiation/convection from calorimeter, calorimeter absorbing heat) are acceptable for M1/M2.
- Alternative method accepted for (b)(i): P = I²R with R = V/I = 4.8 Ω giving P = 2.5² × 4.8 = 30 W.
- Accept 5.40 × 10³ J or 5.4 kJ in (b)(ii); accept 1.72 × 10⁴ J or 17 kJ (2 s.f.) in (c) M2.
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